Hmm...some thoughts on this whole issue, for what they're worth:
As far as we can make out, all matter does seem to operate according to immutable laws (in his UPB book, Stefan argues that matter does behave in this way, though having read Hume and probably Kant as well, he should know why this isn't quite right). Given that all our experiences seem to reflect a law-bound universe, we have no reason to believe that non-material, imperceptible, non-law-bound things like "souls" exist (Stefan seems to think that these things don't exist, but he has no grounds for saying so, since he necessarily can't perceive their nonexistence in any way, and he can't declare them to be conceptually contradictory for the same reason he can't say that all matter operates according to physical laws). If everything that exists in fact operates according to laws, then we're pretty much stuck with determinism.
The metaphysical libertarian (no relation to the political philosophy paradigm) has to say that non-law-bound things actually do exist, in the form of human minds/"souls"/whatever (they don't have to be disembodied, like "souls" are often thought to be). And as far as we don't know that all matter operates according to immutable laws, and we don't know that no non-law-bound things exist, this position does not self destruct (though it must necessarily rest on faith, since it's unclear how one could ever provide decisive or even convincing evidence for it). But Stefan has specifically distanced himself from the two key components of the metaphysical libertarian position by saying that matter does operate according to immutable laws, and that we know that non-material, non-law-bound things don't exist.
And Stefan seems perfectly happy to distance himself from libertarianism. But he also seems to dislike the deterministic position. This strikes me as odd, since it doesn't seem like there's really any alternative. Either there are non-law-bound things or there aren't. If there are (which Stefan denies in his UPB book), then it's possible that libertarianism is true, and if there aren't, then determinism is necessarily true (not fatalism mind you, but Stefan probably wouldn't be happy with the difference).
So why doesn't Stefan like determinism? He accuses determinists of the fallacy of composition, because a whole is not necessarily the sum of the parts, and therefore the lack of free will on the part of any of a person's components does not entail that the person as a whole lacks free will. But Stefan has stated that all matter must abide by immutable laws, and part of what it means to follow immutable laws is that the state of a material thing at time T is the direct result of its state at time (T-1), combined with any external influences that affected it in the interim period. Think of it this way: no component in a car's engine produces horsepower, but an engine produces horsepower. But producing horsepower does not require any of the car's components to violate the laws of physics. If libertarian free will does exist, then the mind would have to be able to produce a non-law-produced change in at least one of the components of the brain. And Stefan has argued that this is impossible. So that takes care of the first part of his podcast. I'm not sure if the next one offers any more reasons, but since I'm pretty sure Stefan's position actually entails determinism, I'm not sure that it's really necessary that I listen to it. If that's not true, I'll do it, but...well...I just don't feel like it.
By the way, I haven't given up on the Molyneux Project; I just need a little bit of a break! Oh, and being made from coal, all diamonds were once alive.